Is there an app available that allows one to automatically backup photos and videos from a mobile device to the home network?

As far as I know, it is not possible. Access the fotos from your phone is possible via Synology Photos

Can I use 2-4TB SSD and use JBOD to get 8 TB storage?

I would say no. Using 2 4TB drives will only give you 4TB storage as one of the two drives is a mirror of the first one for fail-over. This is the purpose of NAS drive system. Synology website will explain the configurations in more detail. There are several excellent YouTube videos online to get more detailed information.

Is your ds223 nas compatible with seagate 8 tb ironwolf harddrives?

Yes, this is exactly what I have in my NAS DS223. 8GB seagate iron wolf. They work really well.

Can I use the HGST WD Ultrastar DC HC320 8TB with the synology ds223?

Did not see it it in compatibility list. From WD only Red Plus series (which I do not recommend - check WDDA alert on Synology in the internet)

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Description

🚀 Elevate your digital workspace with Synology DS223 — storage that works as hard as you do!

MASSIVE STORAGE POWER - Supports up to 36 TB raw capacity to future-proof your digital life.
SEAMLESS FILE SHARING - Synology Drive offers a free, secure file server solution for effortless collaboration.
ULTIMATE PHOTO BACKUP - Synology Photos ensures your memories are automatically backed up and shareable on the go.
SMART SURVEILLANCE READY - Built-in Surveillance Station transforms your NAS into a powerful NVR system.
CROSS PLATFORM COMPATIBILITY - Works flawlessly with Android, iOS, Windows, and macOS devices for total accessibility.

The Synology DiskStation DS223 is a sleek 2-bay NAS designed for home users and small businesses, offering up to 36 TB of raw storage capacity. It features 1 Gbps data transfer, 3 USB ports, and comes preloaded with Synology Drive, Photos, and Surveillance Station software, enabling secure file sharing, mobile photo backup, and network video recording. Compatible across major platforms, this compact, metal-bodied NAS is your all-in-one solution for reliable data backup and smart digital management.

Specifications

Brand	Synology
Manufacturer	Synology, Synology Inc., 9F., No.1, Yuandong Rd., Banqiao Dist., New Taipei City 220632, Taiwan
Model	DS223
Model Name	Value
Product Dimensions	23.24 x 10.8 x 16.51 cm; 1.28 kg
Item model number	DS223
Digital storage capacity	36 TB
Hard Disk Description	Disk-less
Compatible Devices	Android Phone, Windows PC, iPhone, macOS
Mounting Hardware	Main Unit X 1 Accessory Pack X 1 AC Power Adapter X 1 AC Power Cord X 1 RJ-45 LAN Cable X 1 Quick Installation Guide X 1
Number of items	1
Software included	Surveillance Station, Synology Drive, Synology Photos
Batteries Included	No
Batteries Required	No
Data Transfer Rate	1 Gigabits Per Second
Total USB ports	3
Material	Metal
Mounting Type	Floor Mount
Manufacturer	Synology
Country of Origin	India
Item Weight	1 kg 280 g

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