does this kit have both negative and positive alligator clips?

Yes it does have ( Negative - "Black" ) and ( Positive - "Red" ) regardless of the color there both conductors. Have fun with your project. 

Do these have a maximum nominal voltage rating?

yes to much voltage they get hot

how do you connect wires like if you wanna test a relay switch? do they come with wires? how would wires connect?

You can either clamp (with the bendable tabs on the clip) or solder the lead wires onto the clip. You can also buy pre-made test leads. Elenco TL-6 Standard Alligator Lead Set, 10-Piece set on Amazon.

what type of metal are the clips made of?

These are inexpensive clips, so probably chrome plated mild steel. That's my guess.

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⚡ Clip in, clamp down, power up your projects!

MADE IN THE USA - Quality you can trust, supporting local manufacturing standards.
UNMATCHED GRIP POWER - Sturdy jaws ensure a secure hold every time, eliminating slip and frustration.
COMPACT LIGHTWEIGHT - At just 18g and 2.54cm per clip, easy to carry and organize on the go.
PRECISION METAL BUILD - Crafted from durable metal for long-lasting performance and reliability.
COMPLETE 60 PIECE ASSORTMENT - Everything you need in one compact set to tackle any low-voltage electrical task.

The Cal-Hawk CZACA Clip & Clamp Electrical Set by CTT is a 60-piece assortment of durable metal alligator clips designed for low-voltage jumper leads. Featuring sturdy jaws for maximum grip, each lightweight clip measures 2.54 cm and is made in the USA, offering professional-grade reliability in a compact, easy-to-use set.

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Material	Metal
Brand	Cal-Hawk
Item dimensions L x W x H	25 x 25 x 25 Millimeters
Colour	Black
Style	Clamp
UPC	091044261977 786173402666 789542516803
Global Trade Identification Number	00091044261977
Manufacturer	0
Model	CTT-CZACA-X
Product Dimensions	2.54 x 2.54 x 2.54 cm; 18 g
Item model number	CZACA
Exterior	Painted
Manufacturer Part Number	CZACA
Assembly Required	No
Country of Origin	USA
Item Weight	18 g

Cal-Hawk CZACA Clip & Clamp Electrical Set by CTT (60 pc. Alligator Clip Assortment)

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