Can this be used in cold process soap making ?

Not sure why you would want to but yes it could be an added element at the Trace stage. But as a longtime soapmaker myself, I cannot imagine why you would want to.

Why does it smell like soap?

Tapioca has a distinct smell, but doesn't taste like soap.

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Brand	ERAWAN
Package Dimensions	20.29 x 13.11 x 4.8 cm; 453.59 g
Is Discontinued By Manufacturer	No
Item Weight	453 g

Tapioca Starch Powder 16 Oz (Pack of 1) by Erawan

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