can i fill this oil for unicorn bike disk brakes?

Unicorn doesn't make brakes, they do frames. Look at your brakes. If they are Shimano and say "Shimano Mineral Oil" on the reservoir housing at the lever, then that's what they use.

What is the safest thing to do with old used oil?

Don't pour it down the drain of flush it. It is non-toxic mineral oil so you could treat it like old olive oil I guess. Or bacon grease. If you ever burn leaves or wood scraps you could burn it. Good question.

What is the volume of oil in this product? Yet another Amazon listing without relevant details!

The description says 1000 cc (cubic centimeters), which is approximately one quart.

May i apply it to my bicycle chain?

I would not use this product as a chain lube. I would recommend a product like Rock and Roll Gold Standard Chain Lubricant. Pedros and Finish Line also make chain specific lubricants.

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💧 Keep your brakes flawless with Shimano’s pure power boost!

TRUSTED BRAND ASSURANCE - Shimano quality guarantees durability and brake system longevity
SHIMANO OPTIMIZED FORMULA - Engineered specifically for Shimano disc brake systems for peak efficiency
PRECISION 1000 ML CANISTER - Ample volume for multiple brake maintenance sessions
PURE HYDRAULIC MINERAL OIL - Ensures smooth, consistent brake performance without contamination
RELIABLE WEIGHT DIMENSIONS - Compact 907 g canister fits easily in your workshop or garage

Shimano Mineral Oil 1000 ml Canister is a premium hydraulic mineral oil designed specifically for Shimano disc brakes. Packaged in a convenient 1-liter canister weighing 907 grams, it delivers consistent, contamination-free brake fluid to maintain optimal braking performance and system longevity.

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Manufacturer	Shimano
Brand	Shimano
Product Dimensions	22.86 x 15.24 x 7.62 cm; 907 g
Item model number	SM-DB-OIL
Manufacturer part number	SM-DB-OIL
Safety rating	Não aplicável
Item Weight	907 g

Shimano Mineral Oil 1000 ml Canister for Disc Brakes

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